New organo- and amidozinc derivatives of primary amines

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چکیده

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Preparation of sterically congested 1,3,4-oxadiazole derivatives from N-isocyaniminotriphenylphosphorane, aromatic acids, cyclopentanone and primary amines

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reactions of n-isocyaniminotriphenylphosphorane with cyclopentanone have been studied in the presence of aromatic carboxylic acids and primary amines, proceeds smoothly at room temperature under neutral conditions to afford sterically congested 1,3,4-oxadiazole derivatives by an intramolecular aza-wittig cyclization in ch2cl2 in excellent yields. the structures of the products were deduced from...

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ژورنال

عنوان ژورنال: Dalton Trans.

سال: 2014

ISSN: 1477-9226,1477-9234

DOI: 10.1039/c3dt52602j